This review provides a survey of the key-class of Pt-0 complexes of general formula [Pt(N,N`-chelate)(eta(2)-olefin)]. The main spectroscopic, structural and chemical features are discussed, in terms of electronic and steric properties of the ancillary ligands. The versatile reactivity towards electrophiles is described as a very useful entry to Pt-II compounds with a wide assortment of ligands, such as halido, hydrido, hydrocarbyl, organometal, organoelement and carbene fragments, in some cases stabilised for the first time by the careful choice of the N,N`-ligand. Remarkably, the reactions can be an equilibrium, and their relevant thermodynamic parameters have also been collected, thus allowing a thorough discussion of the electronic and steric factors which affect its position. RI De Felice, Vincenzo/F-4702-2012

Three-Coordinate [Pt(N,N '-chelate)(eta(2)-olefin)] Complexes: Synthesis, Properties and Reactions with Electrophiles

ROVIELLO, Giuseppina;
2011

Abstract

This review provides a survey of the key-class of Pt-0 complexes of general formula [Pt(N,N`-chelate)(eta(2)-olefin)]. The main spectroscopic, structural and chemical features are discussed, in terms of electronic and steric properties of the ancillary ligands. The versatile reactivity towards electrophiles is described as a very useful entry to Pt-II compounds with a wide assortment of ligands, such as halido, hydrido, hydrocarbyl, organometal, organoelement and carbene fragments, in some cases stabilised for the first time by the careful choice of the N,N`-ligand. Remarkably, the reactions can be an equilibrium, and their relevant thermodynamic parameters have also been collected, thus allowing a thorough discussion of the electronic and steric factors which affect its position. RI De Felice, Vincenzo/F-4702-2012
File in questo prodotto:
Non ci sono file associati a questo prodotto.

I documenti in IRIS sono protetti da copyright e tutti i diritti sono riservati, salvo diversa indicazione.

Utilizza questo identificativo per citare o creare un link a questo documento: http://hdl.handle.net/11367/29315
Citazioni
  • ???jsp.display-item.citation.pmc??? ND
  • Scopus 14
  • ???jsp.display-item.citation.isi??? 13
social impact