Atom transfer radical polymerization of methylmethacrylate mediated by a naphtyl-nickel(II) phosphane complex

Roma, Antonella De; Yang, Hai Jian; Milione, Stefano; Capacchione, Carmine; Roviello, Giuseppina; Grassi, Alfonso

doi:10.1016/j.inoche.2011.01.019

The ATRP polymerization of styrene, p-chlorostyrene and methylmethacrylate (MMA) in the presence of the trans-chloro(naphtyl)bis(triphenylphosphane)nickel(11) complex was investigated. The polymerization of MMA is well controlled as witnessed by the narrow average molecular weight distribution of the polymer products and the linear increase of the M(n) values vs. polymerization time. NMR analysis of the polymer chain ends confirmed that the ATRP mechanism is operative in the controlled polymerization of this monomer. (C) 2011 Elsevier B.V. All rights reserved.

Titolo:	Atom transfer radical polymerization of methylmethacrylate mediated by a naphtyl-nickel(II) phosphane complex
Autori:	Roma, Antonella De Yang, Hai Jian Milione, Stefano Capacchione, Carmine ROVIELLO, Giuseppina Grassi, Alfonso mostra contributor esterni nascondi contributor esterni
Data di pubblicazione:	2011
Rivista:	INORGANIC CHEMISTRY COMMUNICATIONS
Handle:	http://hdl.handle.net/11367/23053
Appare nelle tipologie:	1.1 Articolo in rivista

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