The geometry around Pt centers of a defined oligomer, trans-{Cl-[Pt(PBu3)2-C C-C6H4-C6H4-C C-](9)Pt(PBu3)(2)-Cl}, was assessed by XAS experiments performed on the basis of the X-ray single crystal structure of a model dinuclear complex transtrans[ClPt(PBu3)(2)-C C-C6H4-C6H4-C C-Pt(PBu3)(2)Cl]. This study allowed to confirm the reliability of XAS experimental data for the elucidation of complicated molecular structures of compounds that cannot be obtained in crystalline form, such as for example organometallic rod-like polymers. (c) 2006 Elsevier B.V. All rights reserved. RI Fratoddi, Ilaria/B-9656-2011; d'Acapito, francesco/J-4911-2012 OI d'Acapito, francesco/0000-0003-2207-6113
Platinum (II) dialkynyl bridged binuclear complex and related multinuclear oligomer: Comparison of EXAFS and X-ray crystal structure studies
ROVIELLO, Giuseppina;
2006-01-01
Abstract
The geometry around Pt centers of a defined oligomer, trans-{Cl-[Pt(PBu3)2-C C-C6H4-C6H4-C C-](9)Pt(PBu3)(2)-Cl}, was assessed by XAS experiments performed on the basis of the X-ray single crystal structure of a model dinuclear complex transtrans[ClPt(PBu3)(2)-C C-C6H4-C6H4-C C-Pt(PBu3)(2)Cl]. This study allowed to confirm the reliability of XAS experimental data for the elucidation of complicated molecular structures of compounds that cannot be obtained in crystalline form, such as for example organometallic rod-like polymers. (c) 2006 Elsevier B.V. All rights reserved. RI Fratoddi, Ilaria/B-9656-2011; d'Acapito, francesco/J-4911-2012 OI d'Acapito, francesco/0000-0003-2207-6113I documenti in IRIS sono protetti da copyright e tutti i diritti sono riservati, salvo diversa indicazione.
